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Download Degradation and Stabilisation of Aromatic Polyesters by Stuart F. Fairgrieve PDF

By Stuart F. Fairgrieve

This booklet offers a comprehenisve survey of the degradation and stabilisation strategies particular to fragrant polyesters, together with thermal, thermo-oxidative, chemical, gentle and radiation degradation and stabilisation. present wisdom of these kinds of elements is mentioned and analysed, and a few feedback made as to extra reviews which would enhance the topic. fabrics lined contain recognized polyesters reminiscent of poly(ethylene terephthalate) and poly(butylene terephthalate), in the course of the much less recognized poly(alkylene naphthalate)s and liquid crystalline polyesters, to "new" ingredients similar to poly(trimethylene terephthalate). additionally lined are a number of the technique of chemically recycling fragrant polyesters into their beginning fabrics and/or different worthy chemical feedstock, together with present examine into advancements in chemistry and economics of such approaches, and data on advertisement firms accomplishing such recycling. With over a thousand references to papers and patents, this booklet presents either a hugely unique resource of data at the degradation and stabilisation of fragrant polyesters in itself, and an invaluable start line for additional research of this subject either by means of educational and commercial employees during this box. these discovering or production fragrant polyester formulations to be used in fibres, movies, packaging, car functions and engineering functions will locate a lot to curiosity them the following. A significant other quantity at the degradation and stabilisation of aliphatic polyesters, with assurance together with degradable fabrics and polyesters made of renewable assets, is presently in guidance.

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Extra resources for Degradation and Stabilisation of Aromatic Polyesters

Example text

In the particular instance of poly(ethylene-co-butylene terephthalate) [90], the main volatile products were butadiene, THF, acetaldehyde and ethylene, and the ratio of acetaldehyde to ethylene increased markedly with increase in ethanediol content in the copolymer. It has been suggested [59] that ethylene is produced in PET thermal degradation by an intermolecular reaction between unsaturated end groups and the -CH2-CH2- chain unit; it may be that the greater flexibility and availability of such units in the ‘PBT’ part of the copolymer would result in higher evolution levels of ethylene, and this could account for this observation.

The major difference between PBT and PET thermal degradation appeared to be the absence of anhydride-containing oligomers. The B C-H hydrogen transfer is noted to be very efficient in PBT, resulting in formation of unsaturated chain ends at temperatures around the processing temperature of the polyester. The unsaturated oligomers can readily undergo another B C-H transfer process to yield butadiene. This process competes with the formation of anhydride-containing oligomers. Formation of anhydride-containing oligomers and concommitant appearance of THF was observed at approximately 400 °C.

Initial degradation was said to occur via the familiar cyclic transition state to provide acid chain ends and unsaturated ends. The subsequent reactions of the unsaturated chain ends were said to proceed in two ways. Initially, it was proposed that degradation occurred via an ionic process to produce THF: ~Ph(C=O)OCH2CH2CH=CH2 + H+ ‡ ~Ph(C=O)OH+CH2CH2CH=CH2 ~Ph(C=O)OH+CH2CH2CH=CH2 ‡ ~Ph(C+=O) + THF It was also noted that water is present as a degradation product, so this may also be involved in THF evolution: 37 Degradation and Stabilisation of Aromatic Polyesters ~Ph(C=O)OH+CH2CH2CH=CH2 + H2O ‡ ~Ph(C=O)OH2+ + THF ~Ph(C=O)OH2+ - H+ ‡ ~Ph(C=O)OH This is said to be followed by ‘concerted ester pyrolysis’ to produce butadiene and an acid chain end: ~Ph(C=O)OCH2CH2CH=CH2 ‡ ~Ph(C=O)OH + CH2=CH-CH=CH2 Simultaneous decarboxylation reactions were also posited in both mechanisms.

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