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Download Design of Heterogeneous Catalysts: New Approaches based on by Umit S. Ozkan PDF

By Umit S. Ozkan

Content material:
Chapter 1 Use of Oxide Ligands in Designing Catalytic energetic websites (pages 1–23): Edward L. Lee and Israel E. Wachs
Chapter 2 optimum layout of Hierarchically based Porous Catalysts (pages 25–58): Marc?Olivier Coppens and Gang Wang
Chapter three Use of Dendrimers in Catalyst layout (pages 59–81): Bert D. Chandler, Jeong?Kyu Lee, Harold H. Kung and Mayfair C. Kung
Chapter four Rational layout recommendations for business Catalysts (pages 83–111): Saeed Alerasool, C. P. Kelkar and Robert J. Farrauto
Chapter five Chiral amendment of Catalytic Surfaces (pages 113–140): Zhen Ma and Francisco Zaera
Chapter 6 Catalytic Nanomotors (pages 141–159): John Gibbs and Yiping Zhao
Chapter 7 Rational layout and High?Throughput Screening of steel Open Frameworks for fuel Separation and Catalysis (pages 161–194): David Farrusseng and Claude Mirodatos
Chapter eight layout of Bimetallic Catalysts: From version Surfaces to Supported Catalysts (pages 195–212): Jeffrey P. Bosco, Michael P. Humbert and Jingguang G. Chen
Chapter nine Self?Assembled fabrics for Catalysis (pages 213–230): Kake Zhu, Donghai Wang and Jun Liu
Chapter 10 Theory?Aided Catalyst layout (pages 231–258): Matthew Neurock
Chapter eleven Use of In Situ XAS strategies for Catalysts' Characterization and layout (pages 259–293): Christophe Geantet and Jean?Marc M. Millet
Chapter 12 Catalyst layout via twin Templating (pages 295–314): Moises A. Carreon and Vadim V. Guliants

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Extra info for Design of Heterogeneous Catalysts: New Approaches based on Synthesis, Characterization and Modeling

Example text

In addition, anchoring of the surface M1Ox species onto the surface M2Ox species may also change their local molecular structures and their related surface reactivity properties. 12 Conclusions It is shown in this chapter that the activity of the supported catalytic active sites can be controlled and designed by oxide ligands. The molecular and electronic characterization of the model supported MOx/SiO2 and surface-modified supported M1Ox/M2Ox/ SiO2 catalyst systems were determined by in situ Raman and UV–Vis spectroscopy, respectively.

4, an uncorrelated random assignment of pore sizes to cylinders on a (regular or random) particle-spanning lattice, as done in several studies, is rarely representative of a real porous catalyst [71]. Furthermore, such network representations might lead to unrealistically high values for the tortuosity. Typically, a catalyst pellet consists of smaller, compacted nanoporous particles. The spaces in between these particles form the macropores. More realistic, therefore, is a macropore network embedding a nanoporous catalyst, with connections between macropores and nanopores.

Mitchell), Climax Molybdenum Company, Ann Arbor, MI, p. 73. R. A. (1979) Chemistry of Catalytic Processes (eds. R. Ciofallo, J. Marschall and B. Leap), McGraw-Hill, New York, p. 390. S. C. (1985) Applied Catalysis A: General, 15, 339. , Haber, J. and Sloczynski, J. (1975) Reaction Kinetics and Catalysis Letters, 2, 81. Deo, G. E. (1994) Journal of Catalysis, 146, 323. M. G. (1995) Environmental Catalysis (eds G. ), SCI, Rome, p. 223. D. P. (1996) Industrial & Engineering Chemistry Research, 35, 978.

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